There are two principal explosive
mechanisms namely:
a) Shock pressure
b) Gas pressure
Chapman and Jouguet proposed the first
theory of detonation in 1899. This was modified by Zeldovich in 1943
and has gone through many improvements since then. Modern computers
have made it easy to apply the theories to explosive compositions and
calculate the expected detonation parameters. Calculated energy
values based on thermochemical and hydrodynamic theories are commonly
quoted by explosive manufacturers.
Different explosives exhibit different
degrees of gas and shock pressure. The extent to which an explosive
possesses these properties is described by the Aquarium test for
bubble energy and shock energy.
On detonation, explosive energy is
converted into mechanical energy, heat and incomplete reaction
products. The initial detonation pressure Pd is quickly reduced to
the explosion pressure Pe and as the gaseous reaction products
expands to fill available voids, it reduces to blasthole pressure Pd.
This pressure is maintained until venting occurs. The relationship
between Pd and the explosion pressure Pe depends on the type of
explosive used. In general the relationship between them is [Pd = n x
Pe] where n lies between 1 and 2. The blasthole pressure Pd will depend
on the extent to which the hole is filled.
The energy transferred from the
explosive charge to the rock will depend on the extent to which the
blasthole is coupled with the explosive charge. Any air-gap will
cushion the blast and will reduce the efficiency of the energy
transfer. This effect is called the decoupling effect. Decoupling factor D which is diameter of
borehole divided by diameter of charge is always greater than or equal to 1.
D is '1' when the explosive charge is fully coupled with the borehole
wall. The smaller the decoupling factor, the
greater will be the blasthole pressure and efficiency of the energy
transfer.
The shock pulse transmitted to the rock
creates stressing resulting in radial compressive strains which tend
to crush the rock close to the borehole, and also tensile hoop
stresses which are concentric to the borehole and cause local radial
cracking. If the transmitted shock pulse is strong in relation to the
confined strength of rock, then considerable initial crushing and
fracturing near the explosive charge is bound to occur (Figure 1).
Figure 1: Process of Rock Breakage
Beyond the fracture zone, the pulse
travels as an elastic wave until it reaches the free face, where the
wave is reflected as a tensile wave. The amount of energy transferred
to a given rock is a linear function of the product of density and
the rate of detonation. This term is called the characteristic
impedance of explosive.
The explosive must be selected to match
with the operational aspects of blasting so that maximum energy could
be transferred to the surrounding rock mass. The ideal one being that
which breaks the rock in tension. If the compressive strength of the
rock is exceeded by the shock pulse then annular rock around the
borehole will be crushed to a fine size, and this powder will
prohibit the propagation of the strain pulse. In addition, increased
amount of dust will be formed.
Out of the energy available in the
explosive, it is estimated that only 3 to 20% is transmitted into
stress waves. The major portion comes out as heat, which is not
wasted but expands the gas products of detonation.
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